Product ID:CARBON DIOXIDE, REFRIGERATED LIQUID, 35645
MSDS Date:01/01/1988
FSC:4210
NIIN:00-202-7858
MSDS Number: BRPBZ

Emergency Phone: 708-272-7500

Info Phone: 708-272-7500 / FAX 708-272-7286

Preparer: DGSC-SSH

Cage: 99539

Telephone: (708) 847-272-7500; 847-272-7500

Cage: 99539

CARBON DIOXIDE

CAS: 124-38-9

RTECS: FF6400000

Fraction By Weight: 99.9%

OSHA PEL 5000 PPM

ACGIH TLV: 5000PPM/30000STEL;93

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL:VAP IN CONCS OF 3-5% BY VOLUME
IN AIR CAUSES INCR RESPIRATION/HDCH; 8-15% CONCS CAUSE HDCH,
NAUSEA, VOMIT, MAY LEAD TO UNCON IF NOT MOVED TO OPEN AIR OR GIVEN
O2; HIGHER CONCS CAUSE RAPID CIRCUL ATORY INSUFFICIENCY LEADING TO
COMA & DEATH. PHYSICAL CNTCT W/ LIQUIFIED/SOLID CO2 CAN CAUSE
FROSTBITE OR FREEZE BURNS
Explanation of Carcinogenicity:PRODUCT CONTAINS NO INGREDIENTS
CURRENTLY CLASSIFIED AS CARCINOGENIC BY NTP, IARC OR OSHA.
Effects of Overexposure:ASPHYXIATION HAZARD. MAY CAUSE FROSTBITE IF
CONTACTS TISSUE.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL:REMOVE TO FRESH AIR. SUPPORT BRTHG (GIVE O2/ARTF RESP)
CALL MD. EYE:IMMED FLUSH W/TEPID WATER IN LARGE QUANTITIES OR
W/STERILE SALINE SOLUTION AT LEAST 15 MIN. GET MD. SKIN:FLUSH
AFFECTED AREA W /LUKEWARM WATER. DO NOT USE HOT WATER. SEE MD
PROMPTLY IF CNTCT RESULTED IN BLISTERING OF DERMAL SURFACE OR DEEP
TISSUE FREEZING. PROMPT MED ATTN MANDATORY. RESCUE PERSONNEL SHOULD
HAVE SCBA.

Flash Point:NONFLAMMABLE
Extinguishing Media:NONFLAMMABLE. ITEM IS A FIRE EXTINGUISHER. USE
MEDIA SUITABLE FOR SURROUNDING FIRE.
Fire Fighting Procedures:NONFLAMMABLE. USE PROCEDURES SUITABLE FOR
SURROUNDING FIRE.
Unusual Fire/Explosion Hazard:NONE. CO2 IS NON-FLAMM INERT GAS. EXPOS
TO FIRE/SEVERE OVERHEATING CAN CAUSE CO2 CYL TO BURST. BULK LIQ
STOR CNTNRS PRESSURIZED. CONSULT MFR/ (SEE SUPP DATA)

Spill Release Procedures:EVACUATE ALL PERSONNEL. USING APPROP PROT
EQUIP, PROVIDE VENT TO AREA/AVOID CNTCT W/SOLID,LIQ & EXCESSIVE
INHAL OF VAP. VALVE OFF CO2 SUPPLY FROM LEAKING/BROKEN COMPONENTS.
DO NOT RE-ENTER AREA UNTIL TLV REQUIREMENTS ARE MET.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:PROVIDE GEN/LOCAL EXHAUST VENT TO MEET
TLV REQUIREMENTS. PROVIDE NIOSH/MSHA APPRVD SUPPLIED AIR/SCBA FOR
USE ABOVE TLV EXPOSURE.
Other Precautions:DO NOT INSTALL STORAGE VESSELS IN SUB SURFACE OR
CLOSED AREAS, OR NEAR EXCESSIVE HEAT OR FLAME.

Respiratory Protection:USE NIOSH/MSHA APPROVED POSITIVE PRESSURE AIR
LINE W/FULL FACEPIECE & ESCAPE AIR SUPPLY OR NIOSH/MSHA APPROVED
SCBA SHOULD BE AVAILABLE FOR EMERGENCY USE.
Ventilation:SUFFICIENT TO PREVENT ACCUMULATION ABOVE TLV. LOCAL EXHAUST
SHOULD BE LOCATED NEAR THE FLOOR.
Protective Gloves:INSULATED & COLD RESISTANT GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MSDS PREPARED BY DGSC-SSH FROM OTHER MSDS CURRENTLY IN HMIS FOR GIVEN
PART NUMBER.

HCC:G3
Boiling Pt:B.P. Text:-109F,-79C
Melt/Freeze Pt:M.P/F.P Text:-109F,-79C
Vapor Pres:SUPP DATA
Spec Gravity:1.65
Solubility in Water:1 TO 1 @60F
Appearance and Odor:COLORLESS, ODORLESS GAS; MILKY WHITE SOLID; WATER
WHITE LIQUID.

Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:NONE

Waste Disposal Methods:CONTAMINATED AREA SHOULD BE VENTILATED
THOROUGHLY. SOLID CARBON DIOXIDE SHOULD BE REMOVED OUT OF DOORS AND
ALLOWED TO SUBLIMATE. DISPOSE I/A/W FEDERAL, STATE AND LOCAL
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.